Basic principles of the theory of electrolytic dissociation. §37. Basic principles of the theory of electrolytic dissociation Examples of problem solving

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1. Compare by structure and properties:
a) Ca0 and Ca2+
b) Cu2+ (hydr) and Cu2+ (nonhydr);
c) H0₂ and H+.

2. Using the solubility table, give examples of five substances that form sulfate - SO₄2- ions - in solutions. Write down the equations for the electrolytic dissociation of these substances.

3. What information does the following equation contain:
Al(NO)= Al3++3NO₃-?
Give the names of the substance and ions.
Al(NO)= Al3++3NO₃-
This equation suggests that the substance aluminum nitrate is a strong electrolyte and in solution dissociates into ions: aluminum cation and nitrate ion.

4. Write down the dissociation equations: iron (III) sulfate, potassium carbonate, ammonium phosphate, copper (II) nitrate, barium hydroxide, of hydrochloric acid, potassium hydroxide, iron (II) chloride. Give the names of the ions.

5. Which of the following substances will dissociate: iron (II) hydroxide, potassium hydroxide, silicic acid, nitric acid, sulfur (IV) oxide, silicon (IV) oxide, sodium sulfide, iron (II) sulfide, sulfuric acid? Why? Write down possible dissociation equations.

6. In writing the equations for stepwise dissociation of sulfuric acid, the equal sign is used for the first step, and the reversibility sign is used for the second. Why?
H₂SO₄= H++HSO₄-
HSO₄-=H++SO₄2-
The dissociation of sulfuric acid occurs completely in the first stage, and partially in the second stage.

Electrolytic dissociation of NaCl.avi

Dissociation occurs in solutions and melts.
Soluble acids dissociate into hydrogen ions and acidic ions.
Soluble bases break down into positively charged metal ions and negatively charged hydroxide ions.
Medium salts dissociate into metal cations and anions of acid residues.
Acid salts decompose into metal and hydrogen cations and anions of acid residues.
Cations are metal ions and hydrogen H
+ .
Anions are ions of acidic residues and hydroxide ions OH – .
Ion charge is numerically equal to the valency of the ion in a given compound.
Use the solubility table to create dissociation equations.
IN chemical formula the sum of the charges of positively charged ions is equal to the sum of the charges of negatively charged ions.

Drawing up acid dissociation equations

(using the example of nitric and sulfuric acids)

Drawing up dissociation equations for alkalis
(soluble bases)

(using the example of sodium and barium hydroxides)

Soluble bases are hydroxides formed by active metal ions:
monovalent: Li + , Na + , K + , Rb + , Cs + , Fr + ;
divalent: Ca 2+, Sr 2+, Ba 2+.

Drawing up salt dissociation equations

(using the example of aluminum sulfate, barium chloride and potassium bicarbonate)


Self-control tasks

1. Write the dissociation equations for the following electrolytes: zinc nitrate, sodium carbonate, calcium hydroxide, strontium chloride, lithium sulfate, sulfurous acid, copper(II) chloride, iron(III) sulfate, potassium phosphate, hydrosulfide, calcium bromide, calcium hydroxychloride, sodium nitrate, lithium hydroxide.
2. Divide substances into electrolytes and non-electrolytes: K 3 PO 4 , HNO 3 , Zn(OH) 2 , BaCl 2 , Al 2 O 3 , Cr 2 (SO 4) 3 , NO 2 , FeBr 3 , H 3 PO 4 , BaSO 4 , Cu(NO 3) 2 , O 2, Sr(OH) 2, NaHSO 4, CO 2, AlCl 3, ZnSO 4, KNO 3, KHS.
Name the electrolyte substances.
3. Make up formulas for substances that can be formed by the following ions:

Name the substances and create equations for their dissociation.

Answers to tasks for self-control

2. Electrolytes :K 3 PO 4 – potassium phosphate, HNO 3 – nitric acid, BaCl 2 – barium chloride, Cr 2 (SO 4) 3 – chromium(III) sulfate, FeBr 3 – iron(III) bromide, H 3 PO 4 – phosphoric acid, Сu(NO 3) 2 – copper(II) nitrate, Sr(OH) 2 – strontium hydroxide, NaHSO 4 – sodium hydrogen sulfate, AlCl 3 – aluminum chloride, ZnSO 4 – zinc sulfate, KNO 3 – potassium nitrate, KHS – potassium hydrosulfide , Zn(OH) 2 – zinc hydroxide, BaSO 4 – barium sulfate.
Non-electrolytes : Al 2 O 3, NO 2, O 2, CO 2.

3.
a) N 2 SO 4, CaSO 4, NaMnO 4, MgI 2, Na 2 CrO 4, etc.;
b) KClO 3, Ba(OH) 2, AlPO 4, H 2 CO 3, etc.;
c) H 2 S, CaCl 2, FeSO 4, Na 2 SO 4, etc.